Publication in RSC Advances

The magnetocaloric properties of Gd(III) coordination polymer [Gd(mes)(H2O)6]n (1), where H3mes stands for trimesic acid, were studied by variable temperature/field magnetizations and heat capacity measurements. Analyses revealed the isothermal magnetic entropy change -SM = 36,0 J K-1 kg-1 at T = 2 K and B = 9 T. Furthermore, the quantitative correlation of the magnetocaloric effect based on the mass concentration of Gd atoms (cm(Gd)) was proposed as -DSM = 39,5cm(Gd)0,364 taking into account the experimental data for more than thirty Gd(III) compounds




Date: 1. jun 2017 | Author: agch

Department of Inorganic Chemistry

Faculty of Science
Palacký University in Olomouc

17. listopadu 12
CZ-771 46 Olomouc
Czech Republic

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